Before synthetic fabrics were developed then wool was used extensively as a waterproof layer.
I rather think that wool of the apropriate type/weave/treatment is readily available these days (replaced by cheap synthetics and now uneconomic to produce) but a good tight-woven/felted oiled wool would most likely be a lot more waterproof than most woolens easily available today.
Personally I find a good Ventile - especially double layered - over a wool layer a warm, comfortable and almost totally waterproof layer system. If that prooves too warm then I usually throw a poncho on over a single Ventile to beat a thorough downpour

I am looking forward to hearing the results of Treadlightlys test as I would prefer to go "all natural" in my clothing.
Most of my outdoor activity now centres around camp due to old injuries making themselves felt - but lat time I spent any time in thrashing rain I was wearing the jacket I made from the fabric Topknot found - a Ventile clone type fabric (ultratight woven cotton but with a surface treatment of some sort of wax that apears to be fire retardant) and even after 30 mins in pouring rain my body was still dry ... my legs in cotton combats were soaking and I was so wet my socks were soaked from water running down my legs!
It was a good thing I was in town doing the Xmas shopping and could go home and get dry!
The fabric of the jacket is so waterresistant that when I put it on a 40degree was with ordinary non-bio powder the jacket did not get cleaned of its construction marks as the water did not penitrate the fabric!
In hot weather the jacket feels as light and comfortable as Ventile...
Having tried various MVP waterproof over the years as part of my paying work I think that mostly they are uncomfortable, overpriced, un-ecco and too shortlived compared to naturals and if you can "manage" water ingress rather than rely on wearing MVPs (like managing wet/dry clothing in the jungle for instance) and stay within your comfort tollerances then great

Let us see how the light footed one gets on with the wool
