Hi, I just saw this tutorial how to make a fire from a potato.
http://www.5min.com/Video/How-to-make-fire-using-a-potato-6894
http://www.5min.com/Video/How-to-make-fire-using-a-potato-6894
I can't tell from that what the wires are made of, if differing materials it should work like a basic salt water battery, just solder on the end of 1 wire might be enough.
Also not sure if the toothpaste is doing anything electrically wise, it may just be keeping a high salt concentration in a small area
Sorry, still stuck on the first bit!
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As a basic potato or salt water battery I wouldn't expect it to produce enough voltage to spark, though if you put a whole bunch in series it might.