i believe (though i may be wrong) that the brit army bashas are made of PU coated nylon, whether you can go ahead and proof with silicone straight on top of PU or not i have no idea, someone will know. if it is leaking then i'd expect to see some evidence of delamination between the nylon and the PU coating, if i couldn't see that then i'd presume that i just didn't have my basha set up very well and leave it 'til next time it rains to have another look. if you can see delamination between the fabric and it's coating then i'm not sure how much help another layer of waterproofing would help.
if you do decide to go down the silicone route then shewie had it about right, clear builders silicone diluted with some white spirit, personally i'd be going for something more like three parts white spirit to one part silicone though. my reason for that is that i wouldn't be painting it on, what i'd do is get a bucket with my solution in it and give the fabric a good soak in the bucke, once the fabric was well and truely wetted i'd take it out and pitch it as flat and taught as i could get it and leave it to dry. whatever you do make sure you don't have any creases or folds in the fabric as it dries because you'll never get them out again, they'll be siliconed together
HTH
stuart