Forgot to mention the amount of insect poisons used in growing cotton. Actually not all synthetics are forever, apparently natures answer to polyamides and polyesters was bacteria that break them up. Polyester fleece is often mentioned for microplastics, true but the same fiber used as pile fabric drops that to almost insignificant level. Sometimes just being clever pays of.Cotton may take a lot to produce - but at least it rots back into the planet instead of polluting it forever as synthetics do ...
So did Germans in WW1 and look what happened to them. I can use linen, never tried hemp (fabric available from Romania) or nettle (fabric available from Germany). I have also heard that a lot of people very much prefer cotton or any cotton derivative to the point that these bast fibers are not really a general alternative.I have had hemp clothing in the past but prefer nettle.
The only real problem with the generally used synthetic fibers is fire, with thick enough fibers they do not burn easily but melt and form holes. There are some very fire resistant fibers available but they are more expensive and the most common, Nomex, has very poor wear characteristics as the fiber splits easily. Wool is much better (I wonder why no one has made a Keratin analog alternative), of course it is not only the material but also the structure. Some proteins and polyamides are chemically not that far apart.