Nettles are quite effective as a dye. They were used for some military cloth during the second world war
They were, but it was the nettle fibre that was used instead of linen or hemp. Both linen and hemp are 'crops' and need arable land while the nettles will grow anywhere that is nitrogen rich, like the back end of a byre where the run off goes. Nettle fibre is softer, shorter and whiter than flax but the nettle doesn't dye itself without a tannin intervention.
I think to dye this size of cotton effectively would need an oil drum sized vat for soaking, heating, etc.,
cheers,
Toddy