There is always a chance that chemicals from the can lining "could" leach into the soup and therefore into your body, however,
.... If you are doing it as a business, there are a few things which you will have to take into account,
You owe them the due diligence of researching what that coating is made from and whether any reports have been made about it causing problems in the human food chain. I believe that you would be right to mention that the soup can be cooked in the can, but that it is up to the individual to decide what risks they wish to accept in their individual future behaviour.
If there is any doubt about it, you will be honour bound (through your risk assessments and best practise method statements) to do all that is "reasonably practicable" to minimise any risk to your customers.
You should also offer them a verbal warning that the soup they are about to eat will be hot - stupid I know, but it is the same reason that forces coffee shops to print the warning on their coffee cups! Without the warning they are in a position to claim against you if they injure themselves on something that is directly attributable to your actions.
Have fun
Ogri the trog