I took my GF with me on a little trip into the woods this summer and asked her what she wanted to do / learn. She came up with shelter and fire. We didn't had the time to make a big and elaborate shelter, but made a small knee high one (debris), to give her an idea on how things work. Explained the principles of fire and how a ferro rod works, and let her loose to make fire: she succeeded.
As there was some knife handling, I showed her how to handle it and pass it on to someone else. Also tried to learn her basic sharpening, but she couldn't be bothered - she doesn't like knives
We kipped on the forest floor, under a Tatonka 3x3 tarp, which she helped to put up, so another shelter aspect covered.
Next time she wants to do bowdrill
After we returned, we watched some bushy series and she started to comment:
- I've done that, that's not so hard
- You don't do it like that
- He didn't purify his water!!!
- I want to learn that
- Cool!
So, I'd say: ask what the newby wants to learn (and how: hands on, observe, simultaneous, etc)