Opinels are available with either carbon steel OR stainless steel blades these days.
As Chris points out, it really doesn't matter whether it's carbon or stainless, what matters is that the spine of the blade has a"sharp" corners. Filing or grinding the back of the blade so that it has a nice, square profile will give you the sort of corners that will scrape materail off the ferro rod properly.
Personally I prefer to carry a small piece of an old hacksaw blade with my ferro rod (if it's one that did not come with a striker) and use that instead of my knife. This means that not only are my fingers kept well away from the cutting edge of my knife (because I'm not using it) but I cannot be tempted to lay the knife down on the ground (leading to possible loss or accident) in my haste to "deal" with the small fire I've just lit.
With good tinder I'll use the straight back of the hacksaw blade to scrape the ferro rod, but if my tinder is poorer I can use the teeth of the hacksaw blade and produce sparks like nothing else I've ever tried will do. Using the teeth like this does tend to wear down the ferro rod quite quickly though, which is why I use the back of the blade when I can.