Being sensible ? Carbon monoxide and Methanol

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Nice65

Brilliant!
Apr 16, 2009
6,486
2,898
W.Sussex
Good posts guys, backed with good documentation. I'm so glad this hasn't gone the way of the "other" thread on this.

Nicely titled OP also myotis :). Sensibility is the name of the game with any flammable material.
 

bigroomboy

Nomad
Jan 24, 2010
443
0
West Midlands
A table in ppm is meant for vapour build up in enclosed spaces. So it doesn't really apply to filling a stove outside. The main hazard I'm our case is spilling on your hand when filling and adsorption through the skin. It can be quite toxic But so can many things it just requires care and being responsible for our own safety.

Maths is not good either. That smell everybody complains about is pyridine which is toxic and especially bad for a mans swimmers. It also has purple dye and denaturing agent commonly wood napha. For me not a better choice then methanol.

B&Q sell bio ethanol at a good price which is basically IMS but you don't need a licence and its quite cheap. Its my choice for alcohol stoves.
 

Gray

Full Member
Sep 18, 2008
2,091
10
Scouser living in Salford South UK

horsevad

Tenderfoot
Oct 22, 2009
92
1
Denmark
A table in ppm is meant for vapour build up in enclosed spaces. So it doesn't really apply to filling a stove outside. The main hazard I'm our case is spilling on your hand when filling and adsorption through the skin. It can be quite toxic But so can many things it just requires care and being responsible for our own safety.

Maths is not good either. That smell everybody complains about is pyridine which is toxic and especially bad for a mans swimmers. It also has purple dye and denaturing agent commonly wood napha. For me not a better choice then methanol.

B&Q sell bio ethanol at a good price which is basically IMS but you don't need a licence and its quite cheap. Its my choice for alcohol stoves.


As I understood the OP, the the question were concerned with vapour build-up in a tent, for which a table of PPM-values would seem fit.

For skin exposure the absorption rate for methanol is quite high, at 0,192mg/cm2/min

(Reference: Dutkiewicz, B., Konczalik, J. & Karwacki, W. (1980). Skin Absorption and Per Os Administration of Methanol in Men. In: International Archives of Occupational and Environmental Health #47, 1980, pp81-88)

On of the well-documented cases of severe systemic health effects from skin absorbtion of methanol is from Poland. A painter accidentially spilled some methanol on his trousers and footwear - and went blind after a few days.
(Reference: Łazariew, N.W. (1954). Noxious substances in industry. Państwowe Wydawnictwo Techniczne, Warszawa)

//Kim Horsevad
 

bigroomboy

Nomad
Jan 24, 2010
443
0
West Midlands
As I understood the OP, the the question were concerned with vapour build-up in a tent, for which a table of PPM-values would seem fit.

For skin exposure the absorption rate for methanol is quite high, at 0,192mg/cm2/min

(Reference: Dutkiewicz, B., Konczalik, J. & Karwacki, W. (1980). Skin Absorption and Per Os Administration of Methanol in Men. In: International Archives of Occupational and Environmental Health #47, 1980, pp81-88)

On of the well-documented cases of severe systemic health effects from skin absorbtion of methanol is from Poland. A painter accidentially spilled some methanol on his trousers and footwear - and went blind after a few days.
(Reference: Łazariew, N.W. (1954). Noxious substances in industry. Państwowe Wydawnictwo Techniczne, Warszawa)

//Kim Horsevad

Assuming the OP has lit the stove and is not just looking at it then it doesn't apply.

I pointed out skin adsorption is a hazard however people are are to do their own research and make their own decisions with what they want to use.

Sent from my Nexus 4 using Tapatalk 4
 

feralpig

Forager
Aug 6, 2013
183
1
Mid Wales
I make Bio diesel, and obviously use Methanol. Personally, I loath the stuff. The smell of it makes me feel sick, the fumes made me choke the one time I got a lung full, and the next morning I felt suicidal.
The processor is now set up so i don't get exposed to the fumes, but the first time I used it, I wanted a batch out a bit quick, and it wasn't quite finished.
The right vapour concentration in the air, and it will explode violently, and it burns with an almost invisible flame. More than one person has had a processor explode.
I'm sure the health risk associated with ingestion have been covered before.
Each to their own, but personally, I would never entertain using it as a cooking fuel.

Edited to add, it needs an ignition source to explode, not suggesting it will spontaneously combust.
 
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santaman2000

M.A.B (Mad About Bushcraft)
Jan 15, 2011
16,909
1,114
67
Florida
Why is it that every time this comes up, you have the 'totally toxic and only idiots use it' or the 'i wash my teeth with it'?
IT'S A FUEL all fuels are dangerous in some way or other.would you wash you hands/drink petrol/paraffin?......

Actually I can remember back in the day when it was quite common for mechanics to use gas (petrol or kerosene (paraffin) to clean grease from their hands or dirty metal bits.
 

santaman2000

M.A.B (Mad About Bushcraft)
Jan 15, 2011
16,909
1,114
67
Florida
I don't get why anyone would want to use Methanol, it has a lower BTU rating than Ethanol

I don't use either (I don't even own an alcohol stove unless you count the Sterno) But I believe it has to do with availability. I've never even seen "meths" over here but methanol is available cheaply in every DIY store in 1 gallon or larger cans for just a few dollars.
 

rik_uk3

Banned
Jun 10, 2006
13,320
24
69
south wales
A lot of the American 'stovies' I talk too use HEET in alcohol stoves santaman which seems to be widely available. A lot of 'Musher' stoves are run on methanol up in the Arctic.
 

HantsScooter

Member
Aug 1, 2013
14
1
Hampshire
Methanol, or - more correctly, methyl alcohol, is actually a rather poor choice for use in connection with food. While most fuels are dangerous or even poisonous methyl alcohol is one of the few which can produce quite severe systemic effects through skin contamination.

Like "Skaukraft", I would not allow the use of methanol on the courses I teach.

Regarding the concentrations needed for producing adverse health effects one could use the following datasheet from CDC as a rough guide:

methanol.jpeg


(Image credit: http://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750029.html)


Like other aspects of wilderness travel - avoiding a risk which can be avoided without diminishing ones other possibilities in the planned travel should always be considered the prudent choice. Being aware of such "hidden" or non-obviois risks is an important aspect of leading or instructing others.

//Kim Horsevad

Better tell the International Union of Pure and Applied Chemistry as their fairly sure the proper name is methanol.;)

Sent from my GT-I9300 using Tapatalk 2
 

myotis

Full Member
Apr 28, 2008
837
1
Somerset, UK.
Having now done a lot more reading on this, a critical discovery for me, is that "on balance" as it isn't straightforward, methanol is LESS toxic than petrol or parafin/kerosene.

As these are the fuels I primarily use, and have used, in the case of parafin, for over 50 years, the methanol/ethanol argument has suddenly become irrelevant.

Using methanol sensibly is no different from using petrol or parafin sensibly.

Yes I know others have already made a similar point, but I hadn't realised the toxicity of other "every day" fuels.

I had allowed myself to be misled into believing methanol was an especially dangerous fuel, where in fact it is ethanol that is an unusually safe one.

Still relevant to those looking for an ultra safe fuel, but if you are using it, for example, to light a primus, then it looks as if you should be more worried about the parafin, than the methanol.

Cheers,

Graham
 

Nice65

Brilliant!
Apr 16, 2009
6,486
2,898
W.Sussex
The thought of sleeping in a tent with something burning away next to me gives me the heebie jeebies.

Me too. Though I use an Oztent for long stay camping I just wouldn't sleep with a flame burning. I have a poncy gas tent heater that I run last thing at night while I get ready for bed. After that it's down to my bag and blanket to keep me warm.

Everyone goes on about adequate ventilation. That's like sleeping with the windows open. Personally, if it's cold out, I prefer to close the vents to conserve any immediate body heat, and let the tent air during the day.
 

Gray

Full Member
Sep 18, 2008
2,091
10
Scouser living in Salford South UK
Having now done a lot more reading on this, a critical discovery for me, is that "on balance" as it isn't straightforward, methanol is LESS toxic than petrol or parafin/kerosene.

As these are the fuels I primarily use, and have used, in the case of parafin, for over 50 years, the methanol/ethanol argument has suddenly become irrelevant.

Using methanol sensibly is no different from using petrol or parafin sensibly.

Yes I know others have already made a similar point, but I hadn't realised the toxicity of other "every day" fuels.

I had allowed myself to be misled into believing methanol was an especially dangerous fuel, where in fact it is ethanol that is an unusually safe one.

Still relevant to those looking for an ultra safe fuel, but if you are using it, for example, to light a primus, then it looks as if you should be more worried about the parafin, than the methanol.

Cheers,

Graham

this is the point i was trying to make when i said i'd be interested to see a comparison table with other fuels.
 

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